CHEMISTRY:
PAPER- I
Atomic Structure:
Bohr’s model and its
limitation de Broglie equation, Heisenberg’s uncertainty principle, quantum
mechanical operators and the Schrodinger wave equation, physical significance
of wave function
and its characteristics
(normalized orthogonal), radial distribution and shapes of s, p, d. and f-orbital’s,
particle in a one-dimensional box, quantization of electronic energies
(qualitative treatment of hydrogen atom).Paul’s Exclusion principle. Hund’s rule
of maximum multiplicity, Afbau principle, Electronic configuration of atoms,
Long form of periodic table including trans law rencium elements. Periodicity
in properties of the elements such as atomic and ionic randomization potential
election affinity, electro negativity and hydration energy.
Nuclear
and Radiation Chemistry:
Structure of nucleus
(shell model), nuclear forces, nuclear stability-NP ration, nuclear binding
energy Kinetics, detection and measurement of radioactivity, artificial
transmutation of elements and nuclear reactions, nuclear fission & fusion,
radioactive isotopes and their applications. Radio cartoon dating, Elementary
ideas of radiation chemistry, radiolysis of water and aqueous solution, unit of
radiation, chemical yield (G-value), Fricke’s dosimetry.
Chemical
Bonding : Valence bond theory (Heitier- London and Pauling-Slater
theories), hybridization, VSEPR theory and molecular orbital energy lever
diagrams, for homo and hetero nuclear diatomic molecules, bond order, bond
length and bond strength, sigma and p-bonds, hydrogen bond, characteristics of
covalent bond.
Chemistry
of s- and p-block elements :
General properties of
s-and p-block elements, chemical reactivity of elements and group trends.
Chemical
behavior with respect of
their hybrids, halides and oxides.
Chemistry
of Transition Elements :
General Characteristics,
variable oxidation stases, complex formation, color, magnetic and catalytic
properties. Comparative study of 4d and 5d transition elements with 3d
analogues with respect to their ionic radii, oxidation stasis and magnetic
properties.
Chemistry
of Lanthanides and Actinides :
Lanthanide contraction,
oxidation stasis, Principles of separation of lanthanides and actinides.
Magnetic and spectral properties of their compounds.
Coordination
Chemistry :
Werner’s Theory of
coordination compounds. IUPAC system of nomenclature, effective atomic number
(EAN) Isomerism in coordination compounds. Valence bond theory and its
limitations. Crystal held theory, Crystal held splitting of d-orbital’s in
octahedral, tetrahedral and square planer complexes. Equation and factors
affecting its magnitude, calculation of Crystal held stabilization energies
(CFSE) for d1 to d9 week and strong field, octahedral complexes, spectro chemical
series. Electronic specter of d-transition metal complexes, types of electronic
transitions, selection rules for electronic transitions, Spectroscopic ground
states for d1 to d10 systems.
Bio-Inorganic
Chemistry:
Essential and trace
elements in biological processes, Metallo porphyrins with special reference to hemoglobin
and myoglobin, Biological role of alkali and alkaline earth metal ions with
special reference to Ca2+.
Preparation,
Properties and Uses of the following Inorganic Compounds :
Heavy water, boric acid,
diorama, hydrazine, hydroxylamine, potassium dichromate, potassium
permanganate, Ce (IV) sulphate and titanium (III) sulphate,
Polymers:
Molecular weight of
polymers by sedimentation light scattering viscosity and osmotic pressure.
Number average and weight average molecular weights, elasticity and
crystallinity of polymers.
Borazines
:
Silicones and
phosphonitrillic halide polymers.
Chemical
Thermodynamics : Thermodynamic functions, Laws of thermodynamics and their applications
to various physico-chemical process. Concept of chemical potential. Glibbs
Duhem equation, Classius-Clapeyron equation, thermodynamic treatment of
colligative properties.
Chemical
Kinetics:
Order and molecularity
of a reaction Rate laws, methods for determining the order of a reaction.
Energy of activation, Colision theory of reaction rate. Steady state approximations.
Transition state, theory of reaction rates, consecutive and side reactions.
Phase
Equilibria:
Phases, components,
degrees of freedom, phase diagram of one and two component systems, Nearest
distribution law,
Applications of distribution law.
Electrochemistry
:
Theory of strong
electrolytes. Debye- Hucket theory of activity coefficient laws of electrolytic
conduction, transport number determination of transport number (Hittorts and
moving boundary method). Applications of conductance for determining the
solubility and solubility products, Ionic equilibria, ionic product of water,
pH, acid-base indicators, common ion effect, buffer solubility buffer index,
buffer capacity solubility product and applications in analysis.
Solid
State Chemistry :
Classification of
solids, seven crystal systems, elements of symmetry in crystals, space lattice
and unit cell,
classification of crystals on the basis of bond types ionic solids, metalic
solids, covalent
solids, and molecular
solids. The close packing of spheres, hexagonal close ionic solids, metalic
solids,
covalent solids, and
molecular solids. The close packing of spheres, hexagonal close packing, cubic
close packing and body centered cubic packing, coordination number and radius
ratio effect. Bargg’s law of X-ray diffraction, powder pattern method, crystal
structure of NaCI and KCI.
Surface
Chemistry:
Stability of and origin
of charge on colloids, Electrokinetic potential. Physical and chemical
absorption, various types of adsorption isotherms. Homogenous and heterogeneous
catalysis enzyme catalysis (Michelis-Menton) equation.
Molecular
Spectra :
Rotational Spectra Rigid
and non-rigid rotator models. Determination of bond distance of diatomic
molecules, linear triatomic molecules isotopic substitution.
Vibrational-Rotational
Spectra:
Hormonic and anthormonic
vibrations, vibrational energies of diatomic molecules, zero point energy,
evaluation of force constant. Fundamental frequencies, overtones, trot bands,
degrees of freedom of polyatomic molecules. Concept of group frequencies.
Raman
Spectra :
Raman effect stokes and
antistokes fines and their intensity difference. Rule of mutual exclusion.
Electronic
Spectra :
Electronic
transitions, Frank condom Principle, Phosphorescene and fluorescence.
PAPER-
II
General
Organic Chemistry :
Electronic displacement
inductive, electromeric and mesmoeric effects, Conjugation
and hyper conjugation,
Resonance and its application to organic compounds, Electrophlies, nuclephlies,
carbocations, carbanions
and free radical. Organic acids and bases. Effects of structure on the strength
of organic acids and bases. Hydrogen bond and its effect on the properties of
organic compounds.
Concepts
of Organic Reaction Mechanism:
Mechanism of addition,
substitution, elimination, reactions and molecular rearrangements, Mechanism of
Electrophilic and nucleophilic automatic substitution. Mechanism of the
following reactions : Aldol condensation, Claims condensation Beckmann
rearrangement, Perkin reaction, Reiner- Tiemann reaction, Cannizaro’s reaction,
Friedel Craft’s reaction, Refonnatisky’s reaction and Wagner-Meerwein
rearrangement.
Aliphatic
Compounds : Chemistry of simple organic compounds belonging to following
classes
with special reference
to the mechanisms of the reactions involved therein, alkanes, alkenes, alkynes alkyl,
halides, alcohol, ethers, thiols aldehydes, ketones, a busnaltruated carbonyl
compounds, acids and their derivatives, amines, aminoacids, hydroxy acids, unsaturated
acids and dibasic acids, Synthetic uses of malonic easier acetoaceliceasier,
Gridnand’s reagent, carbene, diazomethane and phosphoranes.
Carbohydrates:
Classification,
configuration and general reaction of simple monosaccharides. Ozone formation,
mutarotation, pyranose
and furanose structures. Chain lengthening and chain shortening in aidoses and
Kethses. Interconversion
of glucose and fructose.
Stereochemistry
and conformations :
Elements of symmetry, optical
and geometrical isomerism in simple organic compounds. Absolute configuration
(R & S); configurations of geometrical isomers, E & Z notations,
Conformation of mono and distributed cyciohexnaes. Boat and chair form.
Aromatic
Compounds:
Modern structure of
benzene; Concept of aromaticity. Huckle
rule and its simple
application to non-benezenoid aromatic compounds. Activating and deactivating
effect of substituent groups, directive influence. Study of the compounds
containing following groups attached to the alky and benzene ring halogen,
hydroxy, nitro and amino groups. Sulphonic acids, benzaldelyde, salicy dehyde,
acetophenone, Benzoic, salicyclic, phithalic, cannamic and mandelic acids.
Naphthalene
& Pyridine:
Synthesis, structure and
important reactions.
Alkaloids:
General methods of
structure elucidation of alkaloids, chemistry of nicotine.
Organic
Polymers:
Mechanism of
polymerization, polymers of industrial importance, synthetic fibers.
Chemistry
of Living Cells :
A Brief introduction,
chemical constituents, cell membranes, acid base balance, Diffusion and active
transport. Donnan membranes equilibria.
Enzymes
and Coenzymes:
Nomenclature and
characteristics, factors which affect enzyme activity.
NMR
Spectroscopy :
Principle of PMR,
chemical shift, spin-spin coupling, interpretation of PMR spectra of simple
organic molecules,
Evaluation
of analytical Data:
Errors, accuracy and
precision, Relative and standard deviation rejection of doubtful, observations,
t-test, Q-test.
Solvent
Extraction :
Distribution law, Craigs
concept of counter-current distribution, important solvent extraction systems.
Chromatography
:
Classification of Chromatographic
techniques, general principles of absorption, partition exchange, paper and
thin layer chromatography.
Environmental
Chemistry:
Air pollutants and their
toxic effects, depletion of ozone layer effects
of oxides of nitrogen, flurochlorocarbons
and their effect on ozone layer, Greenhouse effect, acid rain.
